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Right next to it, there is a smoking area, and another newer smoking area closer to the koban outside the station exit.
In Ikebukuro the West and East exit are both good, although the East exit is more younger “normal” crowds, and the West exit tends to be more salarymen and red light crowds (including workers heading to and from their shifts, if that’s your thing).
Most establishments are open until 5am, and places like Izakaya and Karaoke often have a flat fee for all-you-can-drink / sing / party until 5am.
While I don’t recommend going to an izakaya for the sole purpose of hooking up with someone (unless you’re bringing that someone there), if you are already there with friends you might just find a table of friendly people (or a cute girl/guy on the way to the bathroom) who you can meet and share laughs with.
Forget canned pickup “lines” or strange techniques and routines, and stay away like the plague from any ideas you might have about “tricking” the girl into sex – the best approach is a simple one. Mention something you’d like to do tonight (your agenda! If you’ve been walking, you can gradually slow to a stop now.
If she’s enjoying herself in your company (it doesn’t really take that much), she might voluntarily miss her last train or agree to come for “Just one drink.” If it’s after last train time (ish), then most people are out for good.